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Intensified biogas purification in a stirred tank

Identifieur interne : 000272 ( Main/Exploration ); précédent : 000271; suivant : 000273

Intensified biogas purification in a stirred tank

Auteurs : Tarsida N. Wedraogo [France] ; Souhila Poncin [France] ; J. Wu [République populaire de Chine] ; Huai Z. Li [France]

Source :

RBID : Hal:hal-01274052

Abstract

The present study aims at intensifying the absorption of carbon dioxide in aqueous phases. For this purpose, a second immiscible liquid phase is used to improve the mass transfer of carbon dioxide in water. Absorption measurements are carried out in a stirred cell by online infrared monitoring of the output carbon dioxide concentration. As dispersed phase, 1-octanol shows an improvement in mass transfer whereas colza oil retards it. Toluene has no significant effect in the range of concentrations investigated. Mass transfer coefficients are determined using a chemical method. Nevertheless, the variety of behaviors could not be explained simply by solubility or variation of mass transfer coefficients. In order to understand the complex gas-liquid-liquid interactions and deduce the mass transfer mechanism between these three phases, surface and interface tension measurements and direct observation of bubbles and droplets are also carried out.

Url:
DOI: 10.1016/j.cep.2014.10.004


Affiliations:


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<div type="abstract" xml:lang="en">The present study aims at intensifying the absorption of carbon dioxide in aqueous phases. For this purpose, a second immiscible liquid phase is used to improve the mass transfer of carbon dioxide in water. Absorption measurements are carried out in a stirred cell by online infrared monitoring of the output carbon dioxide concentration. As dispersed phase, 1-octanol shows an improvement in mass transfer whereas colza oil retards it. Toluene has no significant effect in the range of concentrations investigated. Mass transfer coefficients are determined using a chemical method. Nevertheless, the variety of behaviors could not be explained simply by solubility or variation of mass transfer coefficients. In order to understand the complex gas-liquid-liquid interactions and deduce the mass transfer mechanism between these three phases, surface and interface tension measurements and direct observation of bubbles and droplets are also carried out.</div>
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